Category Archives: *** Major results

The mechanism of protection of catalysts supported in redox hydrogel films

Vincent Fourmond, Stefanie Stapf, Huaiguang Li, Darren Buesen, James Alexander Birrell, Olaf Rüdiger, Wolfgang Lubitz, Wolfgang Schuhmann, Nicolas Plumeré, and Christophe Léger

J. Am. Chem. Soc.,  DOI: 10.1021/jacs.5b01194 Publication Date (Web): April 2, 2015

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Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants

A Abou Hamdan , PP Liebgott , V Fourmond , O Gutierrez-Sanz , A L De Lacey , P Infossi , M Rousset , S Dementin , C Léger,

Proc. natl. Acad. Sc. USA 109 19916-19921 (2012) doi:10.1073/pnas.1212258109

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O2-independent formation of the inactive states of NiFe hydrogenase

A Abou Hamdan , B Burlat , O Gutierrez-Sanz , PP Liebgott , C Baffert , A de Lacey , M Rousset , B Guigliarelli , C Leger and S. Dementin,

Nat. Chem. Biol. 9 15-17 (2013) doi:10.1038/NCHEMBIO.1110

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Understanding and tuning the catalytic bias of hydrogenase

A. Abou Hamdan, S. Dementin, P.-P. Liebgott, O. Gutierrez-Sanz, P. Richaud, A. L. De Lacey, M. Rousset, P. Bertrand, L. Cournac and C. Leger,

J. Am. Chem. Soc. 134 8368-8371 (2012) doi:10.1021/ja301802r

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Rates of intra and intermolecular electron transfers in hydrogenase deduced from steady-state activity measurements

S. Dementin, C. Burlat, V. Fourmond, F. Leroux, P.P. Liebgott, A. Abou Hamdan, C. Leger, M. Rousset, B. Guigliarelli, P. Bertrand,

J. Am. Chem. Soc. 133 10211 (2011) doi: 10.1021/ja202615a

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Relating diffusion along the substrate tunnel and oxygen sensitivity in hydrogenase

P.-P. Liebgott, F. Leroux, B. Burlat, S. Dementin, C. Baffert, Th. Lautier, V. Fourmond, P. Ceccaldi, Ch. Cavazza, I. Meynial-Salles, Ph. Soucaille, J. Fontecilla-Camps, B. Guigliarelli, P. Bertrand, M. Rousset, Ch. Leger.

Nat. Chem. Biol. 6(1) 63-70 (2010) doi:10.1038/nchembio.276

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Experimental Approaches to Kinetics of Gas Diffusion in Hydrogenase

F. Leroux, S. Dementin, B. Burlat, L. Cournac, A. Volbeda, S. Champ, L. Martin, B. Guigliarelli, P. Bertrand, J. Fontecilla-Camps, M. Rousset and C. Leger

Proc. Natl. Acad. Sci. USA 105, 11188 (2008) doi:10.1073/pnas.0803689105

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Changing the ligation of the distal [4Fe4S] cluster in NiFe hydrogenase impairs inter- and intramolecular electron transfers

S. Dementin, V. Belle, P. Bertrand, B. Guigliarelli, G. Adryanczyk-Perrier, A. Delacey, V. M. Fernandez, M. Rousset and C. Leger.

J. Am. Chem. Soc. 128, 5209 (2006) doi:10.1021/ja060233b

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